Ultrafast Double Potential Step Chronoamperometry with the Time Window Down to Submicrosecond

The wall-jet electrode Potential step chronoamperometry

A theory is presented which describes the transient current response to a potential step at a wall-jet electrode, thus defining the “response time” of the electrode. Results are given in the form of a normalized transient as a function of a dimensionless time parameter which permits the analysis of experimental data for electrodes of any geometry and for any solution flow rate.

Potential step chronoamperometry at the wall-jet electrode: experimental

Experimental verification of the theory for the transient current response of a wall-jet electrode to a potential step is given. The systems studied are ferrocyanide and bromide oxidation in a specially designed large volume cell. Good and reproducible agreement between diffusion coefficients determined by this method and independent techniques is found. Optimized conditions, to avoid on the on...

Numerical Simulation of Potential Step Chronoamperometry at Low Concentrations of Supporting Electrolyte

Electrochemical systems are considered for which the concentration of ions in solution is low, and therefore there is an electric field which extends deep into solution away from the electrode surface. Finite difference methods are used to model a potential step chronoamperometry experiment at a microhemisphere electrode. Concentration profiles, potential profiles, and current-time curves are p...

Ultrafast magnetism: down to the nanometre scale.

Two-step Smoothing Estimation of the Time-variant Parameter with Application to Temperature Data

‎In this article‎, ‎we develop two nonparametric smoothing estimators for parameter of a time-variant parametric model‎. ‎This parameter can be from any parametric family or from any parametric or semi-parametric regression model‎. ‎Estimation is based on a two-step procedure‎, ‎in which we first get the raw estimate of the parameter at a set of disjoint time...